Liquid Phase Epitaxy growth, structure and spectroscopy of highly-doped 20 at.% Yb3+:LiYF4 thin films

نویسندگان

چکیده

Highly doped (20 at.%) Yb3+:LiYF4 single-crystalline thin films are grown on (001)-oriented bulk undoped LiYF4 substrates by Liquid Phase Epitaxy using lithium fluoride (LiF) as a solvent. The growth temperature lies around 741 °C (0.5–1 supercooling) and the rate is 1.8–2.6 μm/min. nature of confirmed X-ray diffraction polarized Raman spectroscopy. film morphology studied discussed. spectroscopic properties Yb3+ ions reported, indicating stimulated-emission cross-section 0.88 × 10−20 cm2 at 993.9 nm in π-polarization radiation trapping free lifetime 2F5/2 state 2.00 ms weak concentration-quenching. crystal-field splitting multiplets resolved 12 K. Highly-doped Yb3+:LiYF4/LiYF4 homoepitaxies promising for waveguide thin-disk lasers ~1 μm.

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ژورنال

عنوان ژورنال: Journal of Luminescence

سال: 2021

ISSN: ['1872-7883', '0022-2313']

DOI: https://doi.org/10.1016/j.jlumin.2021.118071